Inside would not be the appropriate preposition. But there are a couple of options.
Shall we meet in the station or in the café.
Shall we meet at the station or in the café.
Shall we meet in the station or at the café.
Shall we meet at the station or at the café.
Hope that helps! :)
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June 9, 2021
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Hi! I’m a native English speaker from South Africa. I’d be happy to chat to you, if you’re keen.