Try our free pinyin charts for iPhone and iPad, or our various free vocab lists. That should get you started. iPad http://itunes.apple.com/us/app/pinyin-chart-hd-learn-all/id492198814 iPhone http://itunes.apple.com/us/app/pinyin-chart-learn-all-chinese/id407215045?mt=8

Personally I think the best way as well as simple way to learn Pinyin：You may buy a Children teaching book to read whilst listening & reading to the tape. Children book is easy to be understood by the foreigners, they are always full of fun. Wishing you progress in your studying 阅读儿童教科书是学习拼音的一种有效方法。它们读起来很有趣、不乏味、易懂好学。 祝你学习进步！

i'm good at pinyin, contact me and i would like help you with it. my skype ID is Jungway. add me.

http://www.italki.com/knowledge/page/Chinese%20Pinyin%20Alphabet%20汉语拼音字母表.htm

1)Download the pinyin chart from http://chinesepod.com/tools/pronunciation 2) Get some pinyin literature. You can download one from http://www.jw.org/index.html?option=QrYQCsVrGZNT 3) Read the book while using the chart to help you pronounce each syllable.