Yes. Although I might say: I work pretty much from the moment I get up till the moment I go to bed. The main change I've suggested is to put "pretty much" after the verb. To me, it is the more natural order.

maybe it's not grammatically perfect, but it is how people generally talk nowadays, so yes it is correct.

I pretty much work from the moment I wake up until I go to sleep. Peter, you would be well understood. Technically though, it would be better if you abandoned the use of the designation "pretty". It is a common fault in American speech going all the way back to the 19th Century at least. The proper expression is as follows: I very much work...etc."

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