大为 often Modify verbs，eg:大为恼火，大为愤怒,but you cant say 大为美丽，而应该说非常美丽。

Sometimes 大为 means 非常. In the ancient China, 大为 is oral Chinese, and nowadays we use it in writing but not often.

yeah, 大为 means 非常，eg. 他大为惊奇。(He is very surprised.) usually it is only used in writing. kinda formal.

看了大家的回复。。国语学的不错。。。我天天用，好像也不能讲清楚

in fact u can leave this word alone. just use 非常 or 很 because for some adjs, u can use 大为+adj, such as 大为恼火 but for others, u cant use 大为. for example we never say 大为好 the only way to control this word is : remember....