帮忙翻一下这段话,谢谢大家!
无机刚性粒子能否同时增韧增强聚合物,是一个理论上或工业上极有意义的课题.近年来,使用偶联剂法处理无机刚性粒子界面,已获得显著的增韧效果[1],但体系的抗张强度往往降低。
以不同含量的白炭黑改性聚乙烯基料获得复合材料为研究对象,利用力学性能测试,研究结果表明:加入偶联剂会增强无机相白炭黑与聚乙烯的结合力,改善了界面结构,相容性得到提高。用硅烷偶联剂改性处理白炭黑填充聚乙烯,其复合体系的冲击强度和断裂伸长率有明显的提高。当白炭黑质量分数低于10%硅烷偶联剂为0.1%时,得到了综合性能较好的聚乙烯/白炭黑复合材料。与纯的聚乙烯相比,拉伸性能、断裂伸长率分别提高,表明了白炭黑粒子被分散于基体中,与基体形成牢固的界面结合,与基体树脂之间的链段发生缠结,形成了有利于加工流动性和力学性能提高的界面结构。但随白炭黑填充量的增大而降低。
无机刚性粒子Inorganic rigid particles
增韧增强toughening reinforcement
聚合物polymer
偶联剂coupling agent
白炭黑SiO2
高密度聚乙烯HDPE
冲击强度impulse strength
断裂伸长率elongation at break
力学性能mechanical propertics
硅烷偶联剂silane coupling agent
拉伸强度 tensile strength
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Answers · 3
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I just left out a sentence in my above answer! below are my complete answer.
Whether the inorganic rigid particles can toughen and reinforce the polymers simultaneously is a very meaningful topic both to the theories and to the industrial applications. Recently, treating the interfaces between those particles with the coupling agent has been reported to have a marked toughening effect on the polymers, at the expense of a lowering of tensile strength of the systems.
Taking the composites, whose substrates made of polyethylene modified by various percentages of silica powder, as the research objects, the results of the mechanical property tests showed that the ones doping with coupling agents tend to increase the bonding force between the silica and the polyethylene, by improving the interface structure and the compatibility. When the mass fraction of silica and that of the silane coupling agent are less than 10% and equal to 1% respectively, the prepared polyethylene/silica composite possesses better overall properties. In comparison with the pure polyethylene, the stretch property and elongation at break were both improved as well, revealing that silica particles were well dispersed within the substrate. The strong interface combinations and the winding of chains between the silica and the resin substrate are conducive to the improvement of processing fluidity and mechanic properties. However, too much filling amount of silica will lead to the opposite consequences.
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Whether the inorganic rigid particles can toughen and reinforce the polymers simultaneously is a very meaningful topic both to the theories and to the industrial applications. Recently, treating the interfaces between those particles with the coupling agent has been reported to have a marked toughening effect on the polymers, at the expense of a lowering of tensile strength of the systems.
Taking the composites, whose substrates made of polyethylene modified by various percentages of silica powder, as the research objects, the results of the mechanical property tests showed that the ones doping with coupling agents tend to increase the bonding force between the silica and the polyethylene, by improving the interface structure and the compatibility. In comparison with the pure polyethylene, the stretch property and elongation at break were both improved as well, revealing that silica particles were well dispersed within the substrate. The strong interface combinations and the winding of chains between the silica and the resin substrate are conducive to the improvement of processing fluidity and mechanic properties. However, too much filling amount of silica will lead to the opposite consequences.
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我想我们这个网站中应该不会有人这么有才:-)
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